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Different types of high-energy ball mills have been developed, including the Spex vibrating mill, planetary ball mill, high-energy rotating mill, and attritors [50]. In the nanotube synthesis, two types of HEBM mills have been used: a vibrating ball mill and a rotating ball mill.

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The ball mill is a tumbling mill that uses steel balls as the grinding media. The length of the cylindrical shell is usually 1–1.5 times the shell diameter (Figure 8.11).The feed can be dry, with less than 3% moisture to minimize ball coating, or slurry containing 20–40% water by weight.

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It is a ball milling process where a powder mixture placed in the ball mill is subjected to high-energy collision from the balls. This process was developed by Benjamin and his coworkers at the International Nickel Company in the late of 1960.